NO₂ — Nitrogen Dioxide Air Quality

Nitrogen dioxide (NO₂) is a reddish-brown gas produced mainly by burning fossil fuels. It is a major contributor to urban air pollution, smog formation, and acid rain — and is directly harmful to the respiratory system.

What is NO₂?

NO₂ belongs to the nitrogen oxides (NOₓ) family. In the lower atmosphere it reacts with volatile organic compounds (VOCs) under sunlight to form ground-level ozone (smog). It also dissolves in water to form nitric acid, contributing to acid rain and fine particle formation.

NO₂ is measured in parts per billion (ppb) or micrograms per cubic meter (μg/m³) — 1 ppb ≈ 1.88 μg/m³ at sea level. The US EPA measures 1-hour averages for its AQI; WHO guidelines use 24-hour and annual averages.

Sources of NO₂

Health Effects of NO₂

Short-term exposure

  • Airway inflammation
  • Respiratory infections
  • Worsening of asthma symptoms
  • Coughing, wheezing, difficulty breathing

Long-term exposure

  • Development of asthma in children
  • Increased risk of respiratory disease
  • Cardiovascular effects
  • Contributes to PM2.5 formation (indirect harm)

NO₂ AQI Breakpoints (US EPA)

Based on 1-hour average concentration.

Concentration (ppb)AQICategory
0–53 ppb0–50Good
54–100 ppb51–100Moderate
101–360 ppb101–150Unhealthy for Sensitive Groups
361–649 ppb151–200Unhealthy
650–1249 ppb201–300Very Unhealthy
1250–1649 ppb301–400Hazardous
1650–2049 ppb401–500Hazardous+

WHO and EPA Standards for NO₂

StandardLimitAveraging Period
WHO (2021)25 μg/m³ (≈13 ppb)24-hour
WHO (2021)10 μg/m³ (≈5 ppb)Annual mean
US EPA NAAQS100 ppb1-hour (98th percentile)
US EPA NAAQS53 ppbAnnual mean
EU Directive200 μg/m³ (≈106 ppb)1-hour (not to exceed 18×/yr)
EU Directive40 μg/m³ (≈21 ppb)Annual mean
India NAAQS80 μg/m³Annual mean

How to Protect Yourself from High NO₂

Frequently Asked Questions

What is a safe NO2 level?

The US EPA 1-hour standard for NO2 is 100 ppb. The WHO guideline is much stricter: 25 μg/m³ (about 13 ppb) for 24-hour average and 10 μg/m³ for annual mean.

Is NO2 worse indoors or outdoors?

Both. Outdoor NO2 primarily comes from traffic. Indoor NO2 from gas stoves and unvented heaters can actually exceed outdoor levels in small, poorly ventilated kitchens — sometimes reaching 400–900 ppb during cooking.

How does NO2 relate to smog?

NO2 is a precursor to ground-level ozone (O3) smog. In sunlight, NO2 reacts with volatile organic compounds (VOCs) to produce ozone. This photochemical smog is most severe on hot, sunny days in polluted cities.